The impact of mesa etching method on IR photodetector current-voltage characteristics
MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING
Authors: Smoczynski, Dariusz; Czuba, Krzysztof; Papis-Polakowska, Ewa; Kozlowski, Pawel; Ratajczak, Jacek; Sankowska, Iwona; Jasik, Agata
Abstract
In the paper, the results of the study on how etching type influences the quality of mesa structures in discrete antimonide-based photodetectors are presented. Devices based on both symmetrical and asymmetrical InAs/ GaSb type-II superlattices (T2SLs) designed for mid-(MWIR) and long-wavelength infrared spectral range, respectively were tested. Mesa structures were formed using photolithography followed by wet or inductively coupled plasma - reactive ion etching. The former was based on H3PO4:C4H6O6:H2O:H2O2 solution, and dry etching was performed in BCl3:Ar plasma. The quality of mesas was evaluated using a scanning electron mi-croscope. The current-voltage characteristics of MWIR photodetectors based on the symmetric T2SL show significantly lower leakage currents for plasma etched devices.
Recovery and regeneration of lithium cobalt oxide from spent lithium-ion batteries through a low-temperature ammonium sulfate roasting approach
JOURNAL OF POWER SOURCES
Authors: Tang, Yiqi; Zhang, Beilei; Xie, Hongwei; Qu, Xin; Xing, Pengfei; Yin, Huayi
Abstract
The operating temperature determines the energy consumption and lithium extraction rate of a pyrometallurgical process. This paper aims to employ a molten ammonium sulfate ((NH4)(2)SO4) assisted roasting approach to recovering and regenerating LiCoO2 from spent lithium-ion batteries (LIBs) at 400 degrees C. First, cathode materials from the spent LIBs are converted to CoSO4 and Li2SO4 via a sulfation roasting approach. Both recovery rates of Li and Co reach over 98% at 400 degrees C for 2h and at an (NH4)(2)SO4/(cathode materials) mass ratio of 4:1 in Ar atmosphere. Then, the obtained Co(OH)(2) and Li2CO3 are used to regenerate LiCoO2 that delivers a specific capacity of over 154 mAh g(-1) at 1C with capacity retention of 94% after 100 cycles. Overall, the molten (NH4)(2)SO4 assisted roasting approach reduces the operating temperature to 400 degrees C while maintaining a high extraction rate of over 98% for both Li and Co, promising an energy-efficient approach to recovering various cathode materials from spent LIBs.