Facile synthesis of N, S-codoped honeycomb-like C/Ni3S2 composites for broadband microwave absorption with low filler mass loading
JOURNAL OF COLLOID AND INTERFACE SCIENCE
Authors: Wang, Lei; Bai, Xiaoyu; Zhao, Ting; Lin, Ying
Abstract
Manufacturing highly efficient microwave absorbents with powerful absorbing intensity, wide effective absorption bandwidth (RL < -10 dB, it means that 90% of the electromagnetic waves enter the absorber and are dissipated) and light weight at low filling loading is still a challenge. In this work, N, S-codoped honeycomb-like C/Ni3S2 composites were synthesized via a freeze-drying approach and following pyrolysis process under Ar atmosphere, using NaCI and sucrose as template and carbon source, respectively. When evaluated as a microwave absorbent, the as-obtained N, S-codoped honeycomb-like C/Ni3S2 composite pyrolyzed at 700 degrees C displayed high performance for microwave absorption including high absorption intensity (the maximum reflection loss of -46.8 dB at 13.4 GHz), broad effective absorbing bandwidth (7.0 GHz, 11.0-18.0 GHz) and relative low filling loading in paraffin (only 10 wt%). Such high performance of microwave absorption could be ascribed to the better impedance matching and stronger damping ability induced by unique honeycomb-like structure and suitable pyrolysis temperature. Importantly, our research might provide a facile and engineering strategy to explore other types of microwave absorbing materials to boost their microwave absorption at low filler loading. (C) 2020 Elsevier Inc. All rights reserved.
Relation of Transthoracic Echocardiographic Aortic Regurgitation to Pressure Half-time and All-Cause Mortality
AMERICAN JOURNAL OF CARDIOLOGY
Authors: Strom, Jordan B.; Gelfand, Eli, V; Markson, Lawrence J.; Tsao, Connie A.; Manning, Warren J.
Abstract
To evaluate the relation of aortic regurgitation (AR) pressure half-time (PHT) on transthoracic echocardiography (TTE) and all-cause mortality, we screened 118,647 baseline TTE reports from 2000 to 2017, to identify patients with any AR and PHT data. Patients with infective endocarditis or previous aortic valve replacement were excluded. The relation of baseline PHT on time to all-cause mortality was evaluated using Cox regression. A total of 2,653 patients were included (73.1 +/- 14.3 years; 53.8% female; PHT, 530 +/- 162 ms). Patients with shorter PHTs more frequently had 3-4+ AR (PHT <= 200 ms vs > 500 ms, 17.9% vs 0.6%, p < 0.0001). Diastolic parameters (E/e', E/A ratio, mitral valve deceleration time, and pulmonary artery systolic pressure) all significantly correlated with PHT (all p < 0.05). Over a median (IQR) follow-up of 8 (4 to 11 years), there were 799 (30.1%) deaths at a median (IQR) of 1.9 (0.4 to 4.3) years. On a univariate basis, a PHT <= 320 ms or > 750 ms was significantly related to increased mortality, even amongst those with nonsevere AR. After multivariable adjustment (in particular for E/e'), PHT was no longer significantly related to death. In conclusion, in this large, single center, retrospective study, AR PHT was not independently related to mortality. While a PHT <= 320 ms was associated with increased mortality in patients without severe AR, this relation was no longer significant after adjusting for diastolic functional variables. Thus, a PHT <= 320 ms in patients without significant AR may indicate prognostically-relevant diastolic dysfunction. (C) 2020 Elsevier Inc. All rights reserved.