Adsorption removal of Cr(VI) by isomeric FeOOH
WATER SCIENCE AND TECHNOLOGY
Authors: Zhang, Di; Liu, Jiaxin; Zhu, Shibei; Xiong, Huixin; Xu, Yiqun
Abstract
The aim of this work is to study the performances of isomeric alpha-, beta-, and gamma-FeOOH (goethite, akaganeite and lepidocrocite, including five samples named as Gth1 and Gth2, Aka1 and Aka2, and Lep, respectively) for removing hexavalent chromium (Cr(VI)) from aqueous solutions. The adsorption mechanisms were explored by kinetic and isothermal experiments. Adsorption efficiencies under the different pH values, anions, and the levels of adsorbate and adsorbent were also measured. Results showed that the Cr(VI) adsorption by isomeric FeOOH could be best described by pseudo-second-order kinetic model. The processes of Cr(VI) isothermal adsorption could be greatly fitted by the Langmuir and Freundlich equations with the high correlation coefficients of R-2 (>0.92). Also, there were the optimum pH values of 3.0-8.0 for FeOOH to adsorb Cr(VI), and their adsorption capacities were tightly related with the active sites of adsorbents. Cr(VI) adsorptions by these adsorbents were easily influenced by H2PO4-, and then SO42-, while there were little effects by Cl-, CO32- and NO3-. These obtained results could provide a potentially theoretical evidence for isomeric FeOOH materials applied in the engineering treatment of the polluted chromate-rich waters.
INSTAR: An Agent-Based Model that integrates existing knowledge to simulate the population dynamics of a forest pest
ECOLOGICAL MODELLING
Authors: Suarez-Munoz, Maria; Bonet-Garcia, Francisco; Hodar, Jose A.; Herrero, Javier; Tanase, Mihai; Torres-Muros, Lucia
Abstract
Pine plantations, very common in the Mediterranean basin, are recurrently affected by forest pests due to intrinsic characteristics (high density, low spatial heterogeneity) and external factors (consistent trend towards a warmer and drier climate). INSTAR is an Agent-Based Model aiming to simulate the population dynamics of the Thaumetopoea pityocampa forest pest. The model has been designed using a modular approach: several interconnected modules (submodels) facilitate the incorporation of new knowledge about the pest biology and can serve as template for the design of other similar models. The model is spatially and temporally explicit and allows its implementation under different climate and land use scenarios. INSTAR is described in detail in this manuscript using the standardized ODD (Overview, Design concepts and Details) protocol. Temperature is known to be one of the main factors modulating the population dynamics of T. pityocampa. In order to be coherent and structurally realistic, INSTAR should faithfully reproduce the effect of this factor on the species' phenology. This requirement has been assessed here through a consistency test of the submodules responsible for species development. This assessment is constituted by a calibration analysis of the pest phenology and a stress test performed by exposing the model to extreme climate inputs. As a result of calibration, the model successfully reproduces the phenology of the species in the simulated study area. Moreover, the stress test confirmed that the model behaves as expected when exposed to extreme input values. The results presented in this manuscript constitute a first internal validation of the development submodels. After this, INSTAR is ready for a deeper analysis consisting on a sensitivity and uncertainty analysis.