High capacity ethidium bromide removal by montmorillonites
KOREAN JOURNAL OF CHEMICAL ENGINEERING
Authors: Wang, Lijuan; Li, Zhaohui; Zhang, Xingrong; Lv, Guocheng; Wang, Xisen
Abstract
Ethidium bromide (EtBr) is commonly used as a reagent to investigate DNA and RNA bonding in biochemistry. However, it is mutagenic and toxic; thus, its removal from the waste solution is of the top priority in lab safety practice. Although many products with high EtBr removal capacities are available on the market, developing new products with low material costs and high removal capacities is still an urgent priority. As the EtBr is in a cationic form Et+ balanced by counterion Br- in aqueous solution, materials with high cation exchange capacity and large specific surface area may have great potential for efficient EtBr removal, Thus, several montmorillonites (MMTs) were evaluated for their EtBr removal capacity and methods of regeneration in this study. Results showed that both external and internal surfaces of MMTs were effective sorption sites for EtBr with a capacity up to 600mg/g. And the waste-laden materials could be regenerated or safely disposed after incineration at 500 degrees C for 2 h. As such, further tests on optimization and manufacturing kits or devices for practical EtBr removal in routine lab practice is of engineering priority, should MMTs be further explored as an effective material for EtBr removal.
In situ decoration of SnS quantum dots on the alpha-SnWO4 nanosheets for superior visible-light photocatalytic performance
APPLIED SURFACE SCIENCE
Authors: Liu, Xuewei; Liang, Bo; Li, Weifeng
Abstract
A novel heterostructure consisting of SnS quantum dots (QDs) and alpha-SnWO4 nanosheets was constructed through the crystallization of amorphous precursor using a one-pot hydrothermal method. The formation of SnS/alpha-SnWO4 heterostructure was confirmed by X-ray diffraction (XRD), transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS) techniques: the SnS QDs with the average particle size of 2.2 nm were uniformly anchored on the surface of alpha-SnWO4 nanosheets. The amorphous alpha-SnWO4 precursor with negative charge can attract the excessive Sn2+ ions and further react with S2- to form SnS/alpha-SnWO4 heterojunction. The intimate contact between SnS QDs and alpha-SnWO4 nanosheets was beneficial to the effective separation of photo-created electron-hole pairs. Thus, the SnS/alpha-SnWO4 nanocomposites exhibited the enhanced photocatalytic activity in the degradation of methyl orange (MO), Rhodamine B (RhB) and tetracycline (TC). The optimal amount of SnS QDs on the alpha-SnWO4 surface was 2 mol%, whose photodegradation efficiency was about 95.56% for MO removal after 90 min visible-light illumination and its degradation rate (0.0338 min(-1)) was 8.7 times higher than that of pure alpha-SnWO4 (0.0039 min(-1)). The trapping experiments evidenced that the O-center dot(2)-, h(+) and (OH)-O-center dot play important roles in the photocatalysis process. The superior photocatalytic performance of SnS/alpha-SnWO4 nanocomposite would be ascribed to the Z-scheme photocatalytic reaction mechanism. A novel heterostructure consisting of SnS quantum dots (QDs) and alpha-SnWO4 nanosheets was constructed through the crystallization of amorphous precursor using a one-pot hydrothermal method. The formation of SnS/alpha SnWO4 heterostructure was confirmed by X-ray diffraction (XRD), transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS) techniques: the SnS QDs with the average particle size of 2.2 nm were uniformly anchored on the surface of alpha-SnWO4 nanosheets. The amorphous alpha-SnWO4 precursor with negative charge can attract the excessive Sn2+ ions and further react with S2to form SnS/alpha-SnWO4 heterojunction. The intimate contact between SnS QDs and alpha-SnWO4 nanosheets was beneficial to the effective separation of photo created electron-hole pairs. Thus, the SnS/alpha-SnWO4 nanocomposites exhibited the enhanced photocatalytic activity in the degradation of methyl orange (MO), Rhodamine B (RhB) and tetracycline (TC). The optimal amount of SnS QDs on the alpha-SnWO4 surface was 2 mol%, whose photodegradation efficiency was about 95.56% for MO removal after 90 min visible-light illumination and its degradation rate (0.0338 min-1) was 8.7 times higher than that of pure alpha-SnWO4 (0.0039 min-1). The trapping experiments evidenced that the center dot O2-, h+ and center dot OH play important roles in the photocatalysis process. The superior photocatalytic performance of SnS/alpha SnWO4 nanocomposite would be ascribed to the Z-scheme photocatalytic reaction mechanism.