Glycogen phosphorylase isoenzyme BB, (GPBB), is an isoenzyme of glycogen phosphorylase which exists in cardiac (heart) and brain tissue. Glycogen phosphorylase catalyzes the rate-limiting step in the degradation of glycogen in animals by releasing glucose-1-phosphate from the terminal alpha-1,4-glycosidic bond. An increase in blood levels of GPBB can be seen in myocardial infarction and unstable angina.
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