NTA-enhanced Pb remediation efficiency by the phytostabilizer Athyrium wardii (Hook.) and associated Pb leaching risk
CHEMOSPHERE
Authors: Yu, Haiying; Zhan, Juan; Zhang, Qingpei; Huang, Huagang; Zhang, Xizhou; Wang, Yongdong; Li, Tingxuan
Abstract
Nitrilotriacetic acid (NTA), a biodegradable chelant, has been promoted to effectively assist Pb phytoextraction, while a few researches available on the phytostabilizer of Athyrium wardii (Hook.). In this study, two incubation experiments and a subsequent column experiment were conducted to investigate the effects of application of NTA on Pb availability in soils and Pb accumulation in A. wardii and associated leaching risk. The application of NTA significantly increased the exchangeable Pb and Pb bound to carbonates along with a decreased pH, leading to enhanced Pb availability in soils. It was more effective in enhancing Pb availability in soils by adding 2 mmol kg(-1) NTA into soils at once for 7 d, thus demonstrating potential for enhancing Pb uptake by A. wardii. After the addition of 2 mmol kg(-1) NTA for 7 d, Pb concentrations in roots of A. wardii was enhanced by 23.8%, along with 10.6% of increase for Pb accumulation in roots. No significant changes were observed for the biomass of A. wardii. Meanwhile, the available Pb and TCLP-extractable Pb in 0-20 cm soils increased by 11.1-23.4% and 7.1-31.2%, thus promoting Pb leaching in 0-20 cm soils. However, there were no changes for Pb leaching risk levels of 20-40 cm soils. No Pb was detected in the leachates from all columns. The application of 2 mmol kg(-1) NTA at once for 7 d is therefore proved to show greater potential in enhancing Pb remediation efficiency by the phytostabilizer of A. wardii without increasing Pb leaching risk into groundwater. (C) 2020 Elsevier Ltd. All rights reserved.
Removal of natural organic matter from aqueous solutions using electrocoagulation pulsed current: optimization using response surface methodology
WATER SCIENCE AND TECHNOLOGY
Authors: de Oliveira, Andre Gadelha; Ribeiro, Jefferson Pereira; Neto, Eliezer Fares Abdala; de Lima, Ari Clecius Alves; Amazonas, Alvaro Amanajas; da Silva, Luiz Thiago Vasconcelos; do Nascimento, Ronaldo Ferreira
Abstract
The use of the pulsed current can be an alternative to decrease the electrode polarization, as well as achieving lower energy consumption. This study investigated the electrocoagulation through pulsed current for the removal of natural organic matter from water. The experiments were carried out using Box-Behnken factorial design with the response surface methodology for the design of experiments, modeling and interpreting of the results. The electrocoagulation cell consisted of an acrylic reactor with 4 L capacity with four electrodes of aluminum, in parallel connection mode. The experimental independent variables studied were: current density (5.5 to 44.5 A m(-2)), electrodes spacing (2 to 7.6 mm), stirring rate (200 to 1,000 rpm), frequency (500 to 5,000 Hz), humic acid concentration (5 to 20 mg L-1) and NaCl (100 to 300 mg L-1) as supporting electrolyte, evaluating the residual apparent color (RAC) and electric energy consumption (EEC). The pH of the solution increased during the experiments, reaching basic values. The response surface regression procedure was employed to fit the second-order polynomial, and the model fitted well to the obtained values, reaching R(2)0.9995 (RAC) and R(2)0.9989 (EEC). The lowest RAC was 11.8 Hazen units (96.2% color removal), where the EEC was 0.393 kWh m(-3).