Rocksalt type Li2Nb0.15Mn0.85O3 without structure degradation or redox evolution upon cycling
JOURNAL OF ALLOYS AND COMPOUNDS
Authors: Abulikemu, Aierxiding; Matsunaga, Toshiyuki; Watanabe, Aruto; Yamamoto, Kentaro; Uchiyama, Tomoki; Nakanishi, Koji; Kawaguchi, Shogo; Osaka, Keiichi; Uchimoto, Yoshiharu
Abstract
Voltage and capacity decay problems of Li2MnO3-based lithium rich layered cathode materials are still unsolved, which are the major barriers for its practical application. Intensive investigations of their mechanisms have been proceeded in recent years, which clarify cation ordered arrangement and spinel deterioration are culprits in structural aspect. Herein, we conduct various analyses to a rocksalt type Li2Nb0.15Mn0.85O3, whose first charge process is along with primary oxygen redox as Li2MnO3, but subsequently shows much better capacity retention. This material suffers from severe voltage decay and overpotential during the cycle but hard X-ray diffraction indicates it can remain rocksalt structure without any tendency of spinel deterioration or cation ordering even with massive lithium vacancies. XAS results further show there is no evident oxygen redox activity from the second cycle, while the redox range of Mn nearly has no change during the cycle. Our results demonstrate that disordered lithium rich cathode materials could be promising to exhibit highly reversible capacity upon long cycling, and their voltage decay problem could be easier to be solved for different mechanism from layered one. (C) 2020 Elsevier B.V. All rights reserved.
Physico-chemical, sensorial and nutritional quality during the harvest season of 'Tango' mandarins grafted onto Carrizo Citrange and Forner-Alcaide no. 5
FOOD CHEMISTRY
Authors: Morales, Julia; Salvador, Alejandra; Besada, Cristina; Navarro, Pilar; Bermejo, Almudena
Abstract
'Tango' mandarin is becoming one of the most demanded varieties in the Mediterranean Region. However, no information on the quality of 'Tango' fruit in this citrus area has been reported. In this study, the physicochemical, nutritional and sensorial quality of 'Tango' mandarins grafted onto Carrizo Citrange and FA5 root-stocks from two locations (Sevilla and Huelva) was evaluated by harvest season. The fruit from Sevilla exhibited lower levels of acids and sugars than those from Huelva, which was associated with a higher sandy soil percentage in the Huelva orchard. In both orchards, the FA5-produced fruit had higher sugars and acids. Flavonoids were affected mainly by location, and the Huelva fruit exhibited the highest levels. The highest vitamin C was for the FA5 fruit. The decreased antioxidant capacity observed throughout the harvest season was related to reduced vitamin C. The sensorial evaluation corroborated changes in the quality parameters.