Estimating and comparing the radiation cancer risk from cone-beam computed tomography and panoramic radiography in pediatric and adult patients
INTERNATIONAL JOURNAL OF RADIATION RESEARCH
Authors: Zamani, H.; Falahati, F.; Omidi, R.; Abedi-Firouzjah, R.; Zare, M. H.; Momeni, F.
Abstract
Background: This study aimed to estimate and compare the absorbed dose, lifetime cancer risk and mortalities due to cone-beam computed tomography (CBCT) and panoramic examinations on patients. Materials and Methods: The exposure factors were applied to 332 patients in two age groups (6-10, and.18-year-old). The dose-area product (DAP) values were measured for CBCT and panoramic radiographies. Organ absorbed doses and effective doses were calculated based on the collected parameters applying PCXMC software. The risk of exposure-induced death (REID) and cancer risks were estimated by BEIR VII phase 2 model at different age groups and genders for the two dental radiography modalities. Results: Salivary glands was the largest contribution of the organ absorbed dose and effective dose in both CBCT and panoramic radiographies. The mean (+/- SD) REID values (per ten million) in CBCT were obtained at 35.6 +/- 5.2 for females and 29.01 +/- 1.8 for males, in the pediatric group, and were 31.1 +/- 2.2 for females and 25.71 +/- 2.02 for males in the adult group for all cancers. In addition, these values for panoramic radiography were 10.2 +/- 1.2 and 6.61 +/- 1.2 for women and men, respectively, in the pediatric group, and were 5.3 +/- 1.06 and 3.01 +/- 1.12 in the adult group. The mean REID values were higher significantly in CBCT compared to panoramic, and also in the pediatric than adult groups (p.0.05). Conclusion: CBCT had a significantly higher level of radiation risks compared to panoramic radiography. Therefore, clinicians should request CBCT examinations by considering their determents and benefits.
Synthesis and Characterization of a 2,3-Dialkoxynaphthalene-Based Conjugated Copolymer via Direct Arylation Polymerization (DAP) for Organic Electronics
POLYMERS
Authors: Jessop, Ignacio A.; Chong, Aylin; Graffo, Linda; Camarada, Maria B.; Espinoza, Catalina; Angel, Felipe A.; Saldias, Cesar; Tundidor-Camba, Alain; Terraza, Claudio A.
Abstract
Poly[(5,5'-(2,3-bis(2-ethylhexyloxy)naphthalene-1,4-diyl)bis(thiophene-2,2 '-diyl))-alt-(2,1,3-benzothiadiazole-4,7-diyl)] (PEHONDTBT) was synthesized for the first time and through direct arylation polymerization (DAP) for use as p-donor material in organic solar cells. Optimized reaction protocol leads to a donor-acceptor conjugated polymer in good yield, with less structural defects than its analog obtained from Suzuki polycondensation, and with similar or even higher molecular weight than other previously reported polymers based on the 2,3-dialkoxynaphthalene monomer. The batch-to-batch repeatability of the optimized DAP conditions for the synthesis of PEHONDTBT was proved, showing the robustness of the synthetic strategy. The structure of PEHONDTBT was corroborated by NMR, exhibiting good solubility in common organic solvents, good film-forming ability, and thermal stability. PEHONDTBT film presented an absorption band centered at 498 nm, a band gap of 2.15 eV, and HOMO and LUMO energy levels of -5.31 eV and -3.17 eV, respectively. Theoretical calculations were performed to understand the regioselectivity in the synthesis of PEHONDTBT and to rationalize its optoelectronic properties. Bilayer heterojunction organic photovoltaic devices with PEHONDTBT as the donor layer were fabricated to test their photovoltaic performance, affording low power-conversion efficiency in the preliminary studies.