The photocatalyzed degradation of ten agrochemicals (simazine, benthiocarb, thiram, diazinon, fenitrothion, isoprothiolane, propyzamide, dichlorvos, fenobucarb, and iprobenfos) has been investigated in an aqueous suspension of TiO2 using a ultra high-pressure mercury lamp (lambda > 290 nm). The degradation is much faster than direct photolysis without TiO2 and depends on the structures of the agrochemicals. As for iprobenfos, the effects of light intensity, wavelength, initial concentration, partial pressure of O-2 in bubbling gases, reaction temperature, and pH on the degradation rate are examined and a kinetic equation is proposed to explain the experimental results. Several intermediates and probable pathways of the degradation are also proposed.