Mass transfer modelling of hollow fiber membrane contactor for apple juice concentration using osmotic membrane distillation
SEPARATION AND PURIFICATION TECHNOLOGY
Authors: Ahmad, Sher; Marson, Gabriela Vollet; Zeb, Waheed; Rehman, Waheed Ur; Younas, Mohammad; Farrukh, Sarah; Rezakazemi, Mashallah
Abstract
The present research study is based on theoretical and experimental investigation of hydrophobic porous hollow fiber membrane contactor (HFMC) module. The mass transfer diffusional model was developed for osmotic membrane distillation (OMD) and applied in apple juice concentration. The mathematical model was developed, taking into consideration the resistance-in-series concept for the mass transfer of water vapor molecules across the hydrophobic HFMC. The model was adapted to include the pore geometry, dimensionless numbers and concentration variation due to viscosity. The water vapor transport model was then simulated in MATLAB (R) and successfully validated with the experimental data. The model was applied to study the effects of driving forces for mass transfer and membrane porosity. Process parameters like juice concentration, stripping solution concentration, and Reynolds number were also studied to evaluate their effect on the overall mass transfer coefficient and water vapor flux. The OMD experiments for the concentration of clarified apple juice were carried out in a laboratory-scale HFMC mini-module composed of two independent circuits, for stripping solution (CaCl2) and apple juice, respectively, in a total recycled mode. For the concentration of clarified apple juice, the evaporation flux ranged from 0.122 to 0.472 kgm(-2)h(-1) resulting in a juice concentration of 30 degrees Brix. The increase in pore diameter from 0.1 to 0.6 mu m resulted in an increase in the mass transfer coefficient from 1.57 x 10(-10) to 7.23 x 10(-10) ms(-1). Similarly, water vapor flux was increased from 0.02 to 0.50 kgm(-2)h(-1) when the activity coefficient was changed from 0.1 to 0.5. Moreover, the results indicated that if the experimental parameters are carefully controlled, the simulation results can be used to predict the OMD process efficiency.
Effect of increasing amounts of postextraction algal residue on straw utilization in steers
JOURNAL OF ANIMAL SCIENCE
Authors: Drewery, M. L.; Sawyer, J. E.; Pinchak, W. E.; Wickersham, T. A.
Abstract
Algal biomass has been identified as a third-generation biofuel. Significant quantities of the coproduct postextraction algal residue (PEAR) remain after lipid extraction. After extraction, PEAR is concentrated in protein (17.9% CP on a DM basis and 32.5% CP on an ash-free basis), suggesting it may be an alternative to cottonseed meal (CSM) as a protein supplement. Our objectives were to determine the optimal level of PEAR supplementation to steers consuming straw and to compare the effects of PEAR supplementation on straw utilization and N metabolism with an isonitrogenous level of CSM. Five steers (198.2 +/- 6.1 kg of BW), in a 5 x 5 Latin square, had ad libitum access to oat straw (80% NDF and 4.5% CP on a DM basis). Treatments were infused ruminally once daily and included no supplemental protein (CON); PEAR at 50, 100, and 150 mg N/kg BW; and CSM at 100 mg N/kg BW. Provision of PEAR increased total digestible OM intake (TDOMI) quadratically (P = 0.01) from 0.9 (CON) to 1.6 kg/d (100 mg N/kg BW of PEAR). Organic matter digestibility (OMD) increased quadratically (P < 0.01) with supplementation and was maximized (55% OMD) at 50 mg N/kg BW of PEAR. At isonitrogenous levels of PEAR and CSM, TDOMI was similar (P = 0.13) as was OMD (P = 0.50). Negative N balance was observed for all treatments except PEAR provided at 100 or 150 mg of N/kg BW. Nitrogen balance was quadratic (P < 0.01) with the greatest retention (1.84 g N/d) occurring at 100 mg N/kg BW of PEAR. There were no differences (P = 0.22) between isonitrogenous PEAR and CSM supplementation in measurements of ruminal ammonia or VFA concentrations. Straw utilization was maximized when PEAR was provided at 100 mg N/kg BW. Our observations suggest cattle provided PEAR utilize straw in a manner similar to those supplemented CSM, indicating PEAR has potential to substitute for CSM as a protein supplement in forage-based operations.