Performance characteristics of a passively locked cavity-enhanced absorption spectrometer with wideband-tunable multimode near-infrared light source
JAPANESE JOURNAL OF APPLIED PHYSICS
Authors: Someya, Ryuta; Imamura, Takeshi; Okamoto, Tetsushi; Hatano, Hiroshi; Toyoshima, Naoko; Tei, Kazuyoku; Yamaguchi, Shigeru
Abstract
A trace material detection system was developed on the basis of cavity-enhanced absorption spectroscopy (CEAS) using a fiber-coupled passively locked external cavity diode laser (PLEC-DL) in the near-infrared (NIR) wavelength region. The oscillation range of an antireflection-coated diode laser (AR-DL) coupled into an external cavity could be simply selected with a narrowband bandpass filter (1 nm), resulting in a stable wavelength oscillation in the wideband tunability between 1640 and 1680 nm. The external cavity acts as a trace material sensor that exhibits excellent flexibility because it is free from the DL source and is carefully designed with mirrors having reflectivities of ca. 99.995 and 99.99%. Trace-level detection was successfully demonstrated with the developed sensor having a minimum detectable absorption coefficient of 2.4 x 10(-8) cm(-1), which corresponds to 0.15 ppm for CH4 concentration without interference from H2O absorption lines under atmospheric pressure. (C) 2016 The Japan Society of Applied Physics
A Guide for Realizing Efficient Polymer Light-Emitting Electrochemical Cells in a Single Active Layer Device Structure
CHEMELECTROCHEM
Authors: Kim, Seunghan; Lee, Jong Ik; Yang, Jeehye; Shin, Ik-Soo; Earmme, Taeshik; Kang, Moon Sung
Abstract
Here, we systematically examine the impact of electrode work function, ionic species, and charge injection layers on the operation of polymer light-emitting electrochemical cells (PLECs) based on p-type Super Yellow. To achieve PLECs yielding a more intensive luminance compared to what can be achieved from the non-ionic light-emitting device counterpart, i. e., the polymer light-emitting diode (PLED), in an analogous device structure, the experimental results here guide the following lessons. First, the use of charge injection layer does not necessarily yield a PLEC that outperforms its PLED counterpart but rather complexes the device structure. Second, injection of minority electrons is critical for enhancing the luminescence characteristics of p-type polymer based LECs, and the enhanced electron injection is achieved more effectively by modifying the work function of the cathode than by changing the cations. Third, for p-type PLECs with a low-work function cathode, careful selection of anions can drastically change the device performance, which are involved in the p-type electrochemically doping process.