H2SO4-doped polybenzimidazole membranes for hydrogen production with acid-alkaline amphoteric water electrolysis
JOURNAL OF MEMBRANE SCIENCE
Authors: Wan, Lei; Xu, Ziang; Wang, Peican; Lin, Yuqun; Wang, Baoguo
Abstract
Acid-alkaline amphoteric water electrolysis is considered as a potential approach for efficient hydrogen production at industrial scale; however, to date synthesized or post-functionized polymer for constructing membranes can hardly meet the requirement of either electrolysis performance or durability aspects. Herein, we synthesize a series of H2SO4-doped PBI-based membranes, including poly (2,2 '-(m-phenylene)-5,5 '-bibenzimidazole) (m-PBI) and poly (4,4 '-diphenylether-5,5 '-bibenzimidazole) (OPBI), for application in acid-alkaline amphoteric water electrolysis system. The H2SO4 doping content, water uptake, swelling ratio, chemical durability and proton conductivity of m-PBI and OPBI membranes are characterized and compared with the perfluorinated sulfonated membrane (Nafion 115). Specifically, the m-PBI membrane doped in 3.0 M H2SO4 attains a current density of 800 mA cm(-2) at cell voltage of 2.0 V at 60 degrees C when applied in an amphoteric water electrolysis, which is superior to the performance of commercial units. Moreover, such system reveals a long-term stability when operating at the current density of 100 mA cm(-2) for 40 h, with an energy consumption of 3.35 kWh m(-3) H-2, offering a possibility for low-energy consumption and scaled hydrogen production technology.
An Integrative Review of Current Practice Models and/or Process of Family-Centered Early Intervention for Children Who Are Deaf or Hard of Hearing
FAMILY & COMMUNITY HEALTH
Authors: Maluleke, Ntsako P.; Khoza-Shangase, Katijah; Kanji, Amisha
Abstract
Over the past few decades, there has been an increasing shift toward emphasizing the importance of the child's family taking an active role in the habilitation process through family-centered early intervention (FCEI) programs. Accordingly, the Health Professions Council of South Africa recommends that early intervention services following confirmation of hearing loss must be family-centered within a community-based model of service delivery that is culturally congruent. The aim of this study was to explore and document current evidence reflecting trends in FCEI for children who are deaf or hard of hearing (DHH) by identifying and describing current practice models and/or processes of FCEI for these children. This study describes our first steps in formulating a framework for FCEI for children who are DHH in South Africa. An integrative literature review was conducted. Sage, Science Direct, PubMed, and Google Scholar databases were searched for studies published in English between January 2009 and January 2019 reporting on FCEI programs for children who are DHH. Studies that focused on the following were excluded from the study: speech and language outcomes of children, youth, and adults who are DHH; education for children who are DHH; universal newborn hearing screening; professionals' roles in early hearing detection and intervention; diagnosis of hearing loss; and sign language. Kappa statistics were performed to determine agreement between reviewers. Twenty-two studies were included in the review. Cohen's kappa revealed a substantial agreement (kappa = 0.8) between reviewers for data extraction and synthesis in terms of the articles that met the criteria for inclusion in the review. Findings were discussed under 5 themes: caregiver involvement; caregiver coaching/information sharing; caregiver satisfaction; challenges with FCEI; and telehealth. Generally, there is sufficient evidence for FCEI, with caregivers indicating the need for full involvement in their children's care. Methods of caregiver involvement involving caregiver coaching/information sharing need to be culturally and linguistically appropriate, with sensitivities around time and manner. This increases caregiver satisfaction with intervention programs and improves outcomes for children who are DHH. Challenges identified by the studies raise implications for early hearing detection and intervention programs, as well as Departments of Health and Social Welfare. These included logistical challenges, professional-related challenges, and caregiver-related challenges. Various aspects of FCEI have been reported in the review. Findings of these studies have significant implications for the formulation of quality FCEI programs to ensure contextually relevant and contextually responsive care of children who are DHH.