Fabrication of novel electrospun Al and Cu doped ZnO thin films and evaluation of photoelectrical and sunlight-driven photoelectrochemical properties
MATERIALS CHEMISTRY AND PHYSICS
Authors: Bakhtiargonbadi, Fatemeh; Esfahani, Hamid; Moakhar, Roozbeh Siavash; Dabir, Fatemeh
Abstract
In this study, the nanostructured ZnO thin films (TFs) doped with Al (AZO) and Cu (CZO) were developed on FTO substrate via electrospinning method and post calcination for the aim of photoelectmchemical (PEC) water splitting. The microstructure, composition and electro-optical properties of the photoanodes were thoroughly characterized using field emission scanning electron microscopy (FESEM), grazing incidence X-ray diffractometer (GIXRD), Raman, photoluminescence (PL), and UV-Vis spectrometers. Microstructural studies revealed that the nanofibmus mats exchanged to the cross linked ZnO nanoparticles (NPs) in the range of 10-20 nm after calcination at 400 degrees C. Furthermore, the electro-optical studies indicated that Al and Cu could separately be incorporated inside the ZnO wurtzite crystal structure. The absorbance of ZnO TFs was increased, while the band gap of ZnO TFs was decreased from 3.19 eV to 3.12 and 3.04 eV upon doping with Al and Cu, respectively. At a bias potential of 0.4 V vs. Ag/AgCl and under AM 1.5 illumination, the doped AZO and CZO TFs exhibited boosted photocurrent densities which were 16.4 and 16.8 times higher than undoped ZnO, respectively. The CZO assay possess the highest photon conversion efficiency owing to the increased light absorption, homogenous sticked NPs, and faster charge transfer. Moreover, electrochemical impedance spectroscopy (EIS) and Mott-Schottky (M - S) assessments showed the separation of electron-hole pairs under light illumination, and that n-type CZO semiconductor had the highest carrier density. Ultimately, our results open new avenues in using industrial friendly and cost-effective electrospinning fabrication method in order to produce highly efficient PEC water splitting photoelectrodes.
Two-terminal artificial synapse with hybrid organic-inorganic perovskite (CH3NH3)PbI3 and low operating power energy (similar to 47 fJ/mu m(2))
JOURNAL OF ALLOYS AND COMPOUNDS
Authors: Ku, Boncheol; Koo, Bonkee; Sokolov, Andrey Sergeevich; Ko, Min Jae; Choi, Changhwan
Abstract
Organiceinorganic hybrid perovskite (CH3NH3)PbX3 [X = I-, Cl-, and Br-] materials were evaluated with memristors for resistive switching (RS) and synaptic functionalities. Analog or multilevel memory behaviors, as well as digital RS characteristics of the Ag/ MAPbI(3)/FTO device structure, were observed in the case of CH3NH3PbI3, whereas (CH3NH3)PbCl3 and (CH3NH3)PbBr3 showed no switching characteristics. The conduction mechanism of RS was dominated by ohmic conduction, space-charge-limited conduction (SCLC), and trap-filled SCLC in both the low-resistance state and the high-resistance state. It is considered that the formation of the b-AgI phase at the interface between Ag and MAPbI(3) thin films resulted in different RS and synaptic function behaviors. We successfully emulated the fundamental synaptic characteristics with only a Ag/MAPbI(3)/FTO memristor, such as the spike-rate-dependent plasticity, paired-pulse facilitation, post-tetanic potentiation, transition from short-term memory to long-term memory, and spike-timing dependent plasticity. The energy consumption of the MAPbI(3)-based memristor was estimated to be as low as 47 fJ/mm(2). Our results indicate that organiceinorganic hybrid perovskite (CH3NH3)PbI3 can be adopted in brain-inspired synaptic devices for hardware-based neuromorphic system applications. (c) 2020 Elsevier B.V. All rights reserved.