Novel thermal barrier coatings repel and resist molten silicate deposits
SCRIPTA MATERIALIA
Authors: Zhang, Baopeng; Song, Wenjia; Wei, Liangliang; Xiu, Yuxuan; Xu, Huibin; Dingwell, Donald B.; Guo, Hongbo
Abstract
Optimization of the resistance of thermal barrier coatings (TBCs) to environmental particles is an area of considerable current research. Here, we present a novel methods, incorporating plasma spray physical vapor deposition (PS-PVD), in order to fabricate a novel yttria-stabilized zirconia (YSZ) TBC which is highly phobic (i.e. nonwettable) with respect to CaO-MgO-Al2O3-SiO2 (CMAS) particles. At 1250 degrees C CMAS particles form liquid droplets which are readily repelled by the TBC surface, diminishing adherence to and penetration into the TBC. This effectiveness of the TBC in resisting wetting by molten CMAS deposits is interpreted to result from its lotus-leaf-like dual-scale microstructure. (C) 2018 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
Treatment of azo dye Acid Orange 52 using ozonation and completed-mixed activated sludge process
29TH SYMPOSIUM OF MALAYSIAN CHEMICAL ENGINEERS (SOMCHE) 2016
Authors: Abidin, C. Z. A.; Fahmi; Ong, S. A.; Ahmad, R.; Sabri, S. N.
Abstract
In this study, the characteristic of colour and COD removal of azo dye Acid Orange 52 (AO52) by ozonation, in combination with complete-mixed activated sludge process (CMAS) was evaluated. The experimentation was arranged in two phases: during the first one, only ozonation was performed, while, during the second phase, it was integrated with CMAS. The performance of colour and COD concentration of AO52 with and without CMAS treatment, is compared and evaluated. From the results, it is obvious that high decolourization from the start of CMAS was contributed from the pre-treatments. The colour removal was due to the fact that ozonation able to cleave the azo bonds that represent colour. Thus, CMAS without pre-treatment are unable to decolourize the dyes sufficiently. 59.6% COD was removed from the first-stage, while merely 9.8% COD fraction removed from the subsequence second-stage CMAS. It is suggested that the rapid COD removal without ozonation are due to activated sludge adsorption processes. The decreased of mixed liquor suspended solids (MLSS) affected the CMAS performances, as the biomass decreased due to lack of nutrient for activated sludge microorganisms to multiply. Results from pre-ozonation alone contributed more than 50% of total COD removal, which indicated that at higher ozone dosage, tend to mineralize azo dye. Thus, ozonation not oxidized the dye though complete mineralization that produce carbon dioxide and water. However, it is a potential process for enhancing colour removal and biodegradability of dye-containing wastewater, once the appropriate ozonation time is determined. Therefore, the role of ozonation seems to break down the dye molecules and created ozonation by-product that is easily biodegraded in the subsequent biological treatment.