Evaluating Solid-Electrolyte Interphases for Lithium and Lithium-free Anodes from Nanoindentation Features
CHEM
Authors: Wang, Wei-Wei; Gu, Yu; Yang, Hao; Li, Sha; He, Jun-Wu; Xu, Hong-Yu; Wu, Qi-Hui; Yan, Jia-Wei; Mao, Bing-Wei
Abstract
The morphology and mechanical property of SEIs for lithium anodes crucially affect the electrochemical cycling performance of Li-metal batteries such as Li-S and Li-O-2 batteries. Herein, we establish the standards for rapidly assessing SEIs for Li and Li-free type of anodes by AFM nanoindentation features toward prediction of corresponding electrochemical performances. A series of single-layered and multi-layered SEIs with known composition and structures are purposely constructed. A set of unique nanoindentation features representative of mechanical properties of the basic SEIs are formed, serving as the standards for rapidly assessing the mechanical properties and electrochemical performances of unknown SEIs together with their Young's modulus, smoothness, and thickness. To validate the applicability of the method, SEIs formed by electrochemical aging and formed on Cu substrates are further evaluated. Our work not only contributes to understanding the influence of SEls on cycling performances but also provides a rapid way for screening SEls.
Interaction between untreated SrTiO3 substrates and solution-derived YBa2Cu3O7-delta films
APPLIED SURFACE SCIENCE
Authors: Piperno, L.; Vannozzi, A.; Pinto, V.; Armenio, A. Angrisani; Rondino, F.; Santoni, A.; Mancini, A.; Rufoloni, A.; Augieri, A.; Tortora, L.; Sotgiu, G.; Celentano, G.
Abstract
In this work it is shown how SrTiO3 substrates interact with YBa2Cu3O7-delta thin films during film processing. The effect of this interdiffusion on morphology and transport properties is analyzed. The films were deposited by low fluorine Metal Organic Decomposition (MOD) on SrTiO3 (0 0 1) single crystals. In general, a sharp c-axis oriented growth and high critical temperature (T-c) were observed in all samples; however, the surface of the otherwise good-quality films is spoiled by the presence of inhomogeneous circular areas of seemingly different appearance and texture. In order to understand the nature of these defects, the substrates and the films were deeply investigated by optical microscopy, scanning and transmission electron microscopy (SEM, TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), contact-stylus surface profilometry (SSP), Atomic Force Microscopy (AFM) and time of flight secondary ion mass spectrometry (ToF-SIMS). The round spots are the manifestation, on the film surface, of ion interdiffusion from the substrate into the YBCO film Spot-free samples can be obtained with different pre-treatments of the SrTiO3 substrates. Although these defects are detrimental for the film local structure, J(c) values are not significantly affected, although the defects' influence might become substantial while working on smaller scales.